Formation of the lithium alkylaluminium secondary amide [Me2Al{(PhCH2)2N}2Li.THF] by a methane elimination amide insertion process

被引：6

作者：

Armstrong, DR ^{[1
]}

Craig, FJ ^{[1
]}

Kennedy, AR ^{[1
]}

Mulvey, RE ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 550卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

ab initio; x-ray diffraction; heterobimetallics; aluminium; amide; lithium;

D O I：

10.1016/S0022-328X(97)00549-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesised by refluxing the amine adduct [Me3Al .(PhCH2)(2)NLi . HN(CH2Ph)(2)] in toluene/THF, the title compound has been structurally characterised by X-ray diffraction, and the methane elimination/amide insertion processes involved in its formation have been modelled theoretically through a series of ab initio MO calculations. (C) 1998 Elsevier Science S.A.

引用

页码：355 / 358

页数：4

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