Frustrated Lewis pairs: reactivities of TMS protected amines and phosphines in the presence of B(C6F5)3

被引：33

作者：

Schulz, Felix ^{[1
]}

Sumerin, Victor ^{[2
]}

Leskela, Markku ^{[2
]}

Repo, Timo ^{[2
]}

Rieger, Bernhard ^{[1
]}

机构：

[1] Tech Univ Munich, WACKER Lehrstuhl Makromol Chem, D-85747 Garching, Germany

[2] Univ Helsinki, Inorgan Chem Lab, Dept Chem, FIN-00014 Helsinki, Finland

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 08期

关键词：

FREE CATALYTIC-HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; METAL-FREE; BULKY PROTON; IMINES; MECHANISM; SELECTIVITY; REDUCTION; COMPLEXES; CLEAVAGE;

D O I：

10.1039/b923196j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

TMS protected amines in combination with B(C6F5)(3) were found to activate H2 and this is followed by a cleavage of the N-Si bond and the generation of TMSH. A TMS protected phosphine on the other hand reacts rapidly with B(C6F5)(3) to give the known compound tBu(2)P(C6F4)B(C6F5)(2) by a facile and efficient route.

引用

页码：1920 / 1922

页数：3

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