Unprecedented ring expansion of [60]fullerene: Incorporation of nitrogen at an open 6,6-ring juncture by regiospecific reduction of oxycarbonylaziridino-[2'3':1,2][60]fullerenes. Synthesis of 1a-aza-1(6a)-homo[60]fullerene, C60H2NH

被引：11

作者：

Banks, MR

Cadogan, JIG

Gosney, I

Henderson, AJ

Hodgson, PKG

Kerr, WG

Kerth, A

LangridgeSmith, PRR

Millar, JRA

Mount, AR

Parkinson, JA

Taylor, AT

Thornburn, P

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] BP INT LTD,RES & ENGN CTR,SUNBURY TW16 7LN,MIDDX,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 04期

关键词：

D O I：

10.1039/cc9960000507

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon treatment with zinc in glacial acetic acid, N-oxycarbonylaziridino[2',3':1,2][60]fullerenes 3 undergo a reversible reductive cleavage of the bridgehead C-C bond to provide the first examples of bridged fulleroids 4 having an open 6,6-ring juncture; deprotection of the N-tert-butoxycarbonyI-derivative 4a allows the convenient synthesis of C60H2NH 5, the parent member of this new class of bridged fulleroids.

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页码：507 / 508

页数：2

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