Blue-emitting heteroleptic iridium(III) complexes suitable for high-efficiency phosphorescent OLEDs

被引：416

作者：

Yang, Cheng-Han

Cheng, Yi-Ming

Chi, Yun ^{[1
]}

Hsu, Chia-Jung

Fang, Fu-Chuan

Wong, Ken-Tsung

Chou, Pi-Tai

Chang, Chih-Hao

Tsai, Ming-Han

Wu, Chung-Chih

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

[2] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

[3] Natl Tsing Hua Univ, Dept Elect Engn, Hsinchu 300, Taiwan

[4] Natl Tsing Hua Univ, Grad Inst Electroopt Engn, Hsinchu 300, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 14期

关键词：

chelate ligands; density functional calculations; iridium; luminescence; N ligands;

D O I：

10.1002/anie.200604733

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dyed-in-the-wool true blue: True-blue phosphorescent organic light-emitting diodes are fabricated by using an IrIII dopant (see picture; gray C; blue N; red Ir; green F). The Ir complex has an enhanced metal-to-ligand charge-transfer contribution, hence a shortened radiative lifetime in the excited state. The maximum external quantum efficiency of the fabricated device is 8.5% and the main emission is around 450 nm. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：2418 / 2421

页数：4

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