Hydrogen-bonding-directed molecular assembly of ferrocene bearing dipeptide chains (-L-Ala-L-Pro-NHPyMe) as an organometallic crystal architecture

被引：31

作者：

Moriuchi, T ^{[1
]}

Yoshida, K ^{[1
]}

Hirao, T ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka 5650871, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 668卷 / 1-2期

基金：

日本学术振兴会;

关键词：

ferrocene; dipeptide; hydrogen bond; chirality organized structure; cocrystal; hydrogen-bonded network; bioorganometallic chemistry;

D O I：

10.1016/S0022-328X(02)02095-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ferrocene 1 bearing the dipeptide chains, -L-Ala-L-Pro-NHPyMe, which was characterized by two intramolecular interchain hydrogen bondings between CO (Ala) and NH (another Ala) of each dipeptide chain to induce the chirality organized structure, was demonstrated to form a 1:2 complex with (1R,3S)-camphoric acid (CA). The single-crystal X-ray structure determination revealed a polymeric cocrystal composed of alternating units of 1 and two CA, which are linked by a network of hydrogen bonds to create the double-helical-like hydrogen-bonded molecular arrangement. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：31 / 34

页数：4

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