Fe3O4 nanoparticles: a robust and magnetically recoverable catalyst for three-component coupling of aldehyde, alkyne and amine

被引：300

作者：

Zeng, Tieqiang ^{[1
,2
]}

Chen, Wen-Wen ^{[2
]}

Cirtiu, Ciprian M. ^{[2
]}

Moores, Audrey ^{[2
]}

Song, Gonghua ^{[1
]}

Li, Chao-Jun ^{[2
]}

机构：

[1] E China Univ Sci & Technol, Shanghai Key Lab Chem Biol, Inst Pesticides & Pharmaceut, Shanghai 200237, Peoples R China

[2] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

GREEN CHEMISTRY | 2010年 / 12卷 / 04期

基金：

加拿大自然科学与工程研究理事会;

关键词：

HIGHLY ENANTIOSELECTIVE SYNTHESIS; C-H ACTIVATION; ONE-POT; TERMINAL ALKYNES; RUTHENIUM HYDROXIDE; EFFICIENT CATALYST; DIRECT-ADDITION; IRON-OXIDE; PROPARGYLAMINES; HYDROGENATION;

D O I：

10.1039/b920000b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A robust, safe and magnetically recoverable Fe3O4 nanoparticle catalyzed three-component coupling of aldehyde, alkyne, and amine (A(3)-coupling) was developed. A diverse range of propargylamines were obtained in moderate to high yield under mild conditions in air. The separation and reuse of the magnetic Fe3O4 nanoparticles were very simple, effective and economical.

引用

页码：570 / 573

页数：4

共 62 条

[41] Three-component coupling of aldehyde, alkyne, and amine catalyzed by silver in ionic liquid [J].

Li, ZG ;

Wei, CM ;

Chen, L ;

Varma, RS ;

Li, CJ .

TETRAHEDRON LETTERS, 2004, 45 (11) :2443-2446

[42] Gold(III) salen complex-catalyzed synthesis of propargylamines via a three-component coupling reaction [J].

Lo, VKY ;

Liu, YG ;

Wong, MK ;

Che, CM .

ORGANIC LETTERS, 2006, 8 (08) :1529-1532

[43] Magnetic nanoparticle-supported Morita-Baylis-Hillan catalysts [J].

Luo, Sanzhong ;

Zheng, Xiaoxi ;

Xu, Hui ;

Mi, Xueling ;

Zhang, Long ;

Cheng, Jin-Pei .

ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (16) :2431-2434

[44] COPPER-CATALYZED REACTION OF TERMINAL ALKYNES WITH NITRONES - SELECTIVE SYNTHESIS OF 1-AZA-1-BUTEN-3-YNE AND 2-AZETIDINONE DERIVATIVES [J].

MIURA, M ;

ENNA, M ;

OKURO, K ;

NOMURA, M .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (16) :4999-5004

[45] Superparamagnetic iron oxide as an efficient catalyst for the one-pot, solvent-free synthesis of α-aminonitriles [J].

Mojtahedi, Mohammad M. ;

Abaee, M. Saeed ;

Alishiri, Tooba .

TETRAHEDRON LETTERS, 2009, 50 (20) :2322-2325

[46] Nanoparticle-Supported and Magnetically Recoverable Ruthenium Hydroxide Catalyst: Efficient Hydration of Nitriles to Amides in Aqueous Medium [J].

Polshettiwar, Vivek ;

Varma, Rajender S. .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (07) :1582-1586

[47] Nanoparticle-supported and magnetically recoverable nickel catalyst: a robust and economic hydrogenation and transfer hydrogenation protocol [J].

Polshettiwar, Vivek ;

Baruwati, Babita ;

Varma, Rajender S. .

GREEN CHEMISTRY, 2009, 11 (01) :127-131

[48] Magnetic nanoparticle-supported glutathione: a conceptually sustainable organocatalyst [J].

Polshettiwar, Vivek ;

Baruwati, Babita ;

Varma, Rajender S. .

CHEMICAL COMMUNICATIONS, 2009, (14) :1837-1839

[49] MULTICOMPONENT ONE-POT ANNULATIONS FORMING 3 TO 6 BONDS [J].

POSNER, GH .

CHEMICAL REVIEWS, 1986, 86 (05) :831-844

[50]

Sakaguchi S, 2001, ANGEW CHEM INT EDIT, V40, P2534, DOI 10.1002/1521-3773(20010702)40:13<2534::AID-ANIE2534>3.0.CO

← 1 2 3 4 5 6 7 →