Aspects of organic chemistry of fullerenes

被引：30

作者：

Hirsch, A ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1997年 / 58卷 / 11期

关键词：

fullerenes; addition reactions; carbon allotropes;

D O I：

10.1016/S0022-3697(97)00058-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Successive additions to [60]fullerene show a remarkable degree of regioselectivity. Two characteristic examples of additions, namely nucleophilic cyclopropanations of 6-6 double bonds as well as formations of 5-6 bridged open azafulleroids, have been systematically investigated by analytical, spectroscopic as well as by computational methods. Regioselective additions to activated positions within the car bon framework of fullerene derivatives are the key steps for both controlled ring opening of the fullerene core and the synthesis of heterofullerenes. (C) 1997 Elsevier Science Ltd.

引用

页码：1729 / 1740

页数：12

共 45 条

[1] FORMATION OF HYDRIDES OF FULLERENE-C-60 AND FULLERENE-C-70 [J].

AVENT, AG ;

DARWISH, AD ;

HEIMBACH, DK ;

KROTO, HW ;

MEIDINE, MF ;

PARSONS, JP ;

REMARS, C ;

ROERS, R ;

OHASHI, O ;

TAYLOR, R ;

WALTON, DRM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (01) :15-22

[2] DIRECTING EFFECTS IN A FULLERENE EPOXIDE ADDITION - FORMATION AND STRUCTURAL CHARACTERIZATION OF (ETA-2-C60O)IR(CO)CL(P(C6H5)3)2 [J].

BALCH, AL ;

COSTA, DA ;

LEE, JW ;

NOLL, BC ;

OLMSTEAD, MM .

INORGANIC CHEMISTRY, 1994, 33 (10) :2071-2072

[3]

Beckhaus H. -D., 1992, ANGEW CHEM, V104, P69

[4]

BINGEL C, 1995, LIEBIGS ANN, P1551

[5] CYCLOPROPYLATION OF FULLERENES [J].

BINGEL, C .

CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (08) :1957-1959

[6] Chirality in fullerene chemistry [J].

Diederich, F ;

Thilgen, C ;

Herrmann, A .

NACHRICHTEN AUS CHEMIE TECHNIK UND LABORATORIUM, 1996, 44 (01) :9-&

[7] Regiochemistry of twofold additions to [6,6] bonds in C-60: Influence of the addend-independent cage distortion in 1,2-monoadducts [J].

Djojo, F ;

Herzog, A ;

Lamparth, I ;

Hampel, F ;

Hirsch, A .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (12) :1537-1547

[8] A MULTIPLY-SUBSTITUTED BUCKMINSTERFULLERENE (C60) WITH AN OCTAHEDRAL ARRAY OF PLATINUM ATOMS [J].

FAGAN, PJ ;

CALABRESE, JC ;

MALONE, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (24) :9408-9409

[9] RING EXPANSION OF THE FULLERENE CORE BY HIGHLY REGIOSELECTIVE FORMATION OF DIAZAFULLEROIDS [J].

GROSSER, T ;

PRATO, M ;

LUCCHINI, V ;

HIRSCH, A ;

WUDL, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (12) :1343-1345

[10]

GROSSER T, 1995, ANGEW CHEM, V107, P1462

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