Aspects of organic chemistry of fullerenes

被引：30

作者：

Hirsch, A ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1997年 / 58卷 / 11期

关键词：

fullerenes; addition reactions; carbon allotropes;

D O I：

10.1016/S0022-3697(97)00058-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Successive additions to [60]fullerene show a remarkable degree of regioselectivity. Two characteristic examples of additions, namely nucleophilic cyclopropanations of 6-6 double bonds as well as formations of 5-6 bridged open azafulleroids, have been systematically investigated by analytical, spectroscopic as well as by computational methods. Regioselective additions to activated positions within the car bon framework of fullerene derivatives are the key steps for both controlled ring opening of the fullerene core and the synthesis of heterofullerenes. (C) 1997 Elsevier Science Ltd.

引用

页码：1729 / 1740

页数：12

共 45 条

[11] OXIDATION OF [60]FULLERENE BY CYTOCHROME-P450 CHEMICAL-MODELS [J].

HAMANO, T ;

MASHINO, T ;

HIROBE, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (15) :1537-1538

[12] REGIOCHEMISTRY OF THE BISOSMYLATION OF C-60 - ORTHO, META, AND PARA IN 3-DIMENSIONS [J].

HAWKINS, JM ;

MEYER, A ;

LEWIS, TA ;

BUNZ, U ;

NUNLIST, R ;

BALL, GE ;

EBBESEN, TW ;

TANIGAKI, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (20) :7954-7955

[13] ASYMMETRIC BISOSMYLATION OF C-60 - NOVEL CHIRAL PI-SYSTEMS [J].

HAWKINS, JM ;

MEYER, A ;

NAMBU, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) :9844-9845

[14]

Henderson C. C., 1994, ANGEW CHEM, V706, P803

[15] C60H4 - KINETICS AND THERMODYNAMICS OF MULTIPLE ADDITION TO C-60 [J].

HENDERSON, CC ;

ROHLFING, CM ;

ASSINK, RA ;

CAHILL, PA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (07) :786-788

[16] MULTIPLE CYCLOPROPANATIONS OF C-70 - SYNTHESIS AND CHARACTERIZATION OF BIS-ADDUCTS, TRIS-ADDUCTS, AND TETRAKIS-ADDUCTS AND CHIROPTICAL PROPERTIES OF BIS-ADDUCTS WITH CHIRAL ADDENDS, INCLUDING A RECOMMENDATION FOR THE CONFIGURATIONAL DESCRIPTION OF FULLERENE DERIVATIVES WITH A CHIRAL ADDITION PATTERN [J].

HERRMANN, A ;

RUTTIMANN, M ;

THILGEN, C ;

DIEDERICH, F .

HELVETICA CHIMICA ACTA, 1995, 78 (07) :1673-1704

[17] FULLERENE CHEMISTRY IN 3 DIMENSIONS - ISOLATION OF 7 REGIOISOMERIC BISADDUCTS AND CHIRAL TRISADDUCTS OF C-60 AND DI(ETHOXYCARBONYL)METHYLENE [J].

HIRSCH, A ;

LAMPARTH, I ;

KARFUNKEL, HR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (04) :437-438

[18] SYNTHESIS OF ISOMERICALLY PURE ORGANODIHYDROFULLERENES [J].

HIRSCH, A ;

GROSSER, T ;

SKIEBE, A ;

SOI, A .

CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (04) :1061-1067

[19] REGIOCHEMISTRY OF MULTIPLE ADDITIONS TO THE FULLERENE CORE - SYNTHESIS OF A T-H-SYMMETRICAL HEXAKISADDUCT OF C-60 WITH BIS(ETHOXYCARBONYL)METHYLENE [J].

HIRSCH, A ;

LAMPARTH, I ;

GROSSER, T ;

KARFUNKEL, HR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) :9385-9386

[20]

Hirsch A, 1994, CHEM FULLERENES

← 1 2 3 4 5 →