Synthesis, Crystal Structure, and Luminescent Activity of 3D Supramolecular Cadmium(II) Complex Constructed From 2,5-Pyridine Dicarboxylic Acid

被引：7

作者：

Gangu, Kranthi Kumar ^{[1
]}

Mukkamala, Saratchandra Babu ^{[1
]}

机构：

[1] GITAM Univ, Dept Chem, Visakhapatnam 530045, Andhra Pradesh, India

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 01期

关键词：

hydrothermal synthesis; crystal structure; supramolecular network; photoluminescence; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; FRAMEWORK; LIGANDS; CHAIN; PHOTOLUMINESCENCE; PROPERTY;

D O I：

10.1080/15533174.2014.900788

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D supramolecular cadmium(II) complex, [Cd(Pydc)(2)(H2O)(2)].H2O(1), (Pydc = 2,5-pyridine dicarboxylate) has been synthesized under mild hydrothermal conditions. In the complex, the two adjacent Cd(II) atoms were bound together by two -oxo bridging and generated an infinite straight chains in 2D layer structure. The non-covalent interactions such as - stacking interactions between pyridyl rings are involved in strengthening of 2D structure and hydrogen bond interactions between two adjacent chains through lattice water molecules led to form an extended 3D supramolecular network structure. Moreover, complex 1 exhibits blue emission at 437nm after photo excitation at 365nm.

引用

页码：98 / 103

页数：6

共 26 条

[1]

Adamson A.W., 1975, Concepts of Inorganic Photochemistry

[2]

[Anonymous], 1997, SHELXS 97 PROGRAM RE

[3] Coexistence of magnetization relaxation and dielectric relaxation in a single-chain magnet [J].

Bai, Yue-Ling ;

Tao, Jun ;

Wernsdorfer, Wolfgang ;

Sato, Osamu ;

Huang, Rong-Bin ;

Zheng, Lan-Sun .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) :16428-16429

[4] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].

Banerjee, Rahul ;

Phan, Anh ;

Wang, Bo ;

Knobler, Carolyn ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2008, 319 (5865) :939-943

[5] Hydrolytic ring opening reactions of anhydrides for first row transition metal dicarboxylate complexes [J].

Baruah, Abhilasha M. ;

Karmakar, Anirban ;

Baruah, Jubaraj B. .

POLYHEDRON, 2007, 26 (15) :4518-4524

[6] Synthesis, crystal structure and photo luminescent property of a 3D metal-organic hybrid of Cd(II) constructed by two different bridging carboxylate [J].

Bhattacharya, Biswajit ;

Dey, Rajdip ;

Ghoshal, Debajyoti .

JOURNAL OF CHEMICAL SCIENCES, 2013, 125 (03) :661-666

[7] Hydrothermal synthesis and structural characterization of Zn(II)- and Cd(II)-pyridine-2,3-dicarboxylate 2D coordination polymers, {(NH4)2[M(μ-pydc)2]•2H2O}n [J].

Colak, Alper Tolga ;

Pamuk, Gonul ;

Yesilel, Okan Zafer ;

Yuksel, Fatma .

SOLID STATE SCIENCES, 2011, 13 (12) :2100-2104

[8] Different Structural Networks Determined by Variation of the Ligand Skeleton in Copper(II) Diphosphinate Coordination Polymers [J].

Costantino, Ferdinando ;

Ienco, Andrea ;

Midollini, Stefano .

CRYSTAL GROWTH & DESIGN, 2010, 10 (01) :7-10

[9] ZnII/CdII-coordination polymers from 1D chain, 2D layer to 3D framework with imidazole-based dicarboxylate ligand [J].

Dong, Wen-Wen ;

Li, Dong-Sheng ;

Zhao, Jun ;

Wu, Ya-Pan ;

Meng, Cai-Xia ;

Wang, Yao-Yu .

INORGANICA CHIMICA ACTA, 2012, 384 :260-265

[10] Hydrothermal synthesis, crystal structure and photoluminescent properties of a novel 3-D coordination polymer [Cd2(pydc)2(H2O)]n (pydc = pyridine-2,3-dicarboxylate) [J].

Han, Zheng-Bo ;

Ma, Yi ;

Sun, Zhen-Gang ;

You, Wan-Sheng .

INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (08) :844-847

← 1 2 3 →