Alcoholysis of 2,2′-pyridil, (2-C5H4N)C(O)C(O)(2-C5H4N), in the presence of copper(II):: A family of planar pentanuclear copper(II) complexes stabilized by [(2-C5H4N)C(O)(OR)C(O)(OR)(2-C5H4N)]2- and carboxylate ligands

被引：49

作者：

Papaefstathiou, GS

Raptopoulou, CP

Tsohos, A

Terzis, A ^{[1
]}

Bakalbassis, EG

Perlepes, SP

机构：

[1] NCSR Demokritos, Inst Sci Mat, Aghia Paraskevi 15310, Greece

[2] Univ Patras, Dept Chem, Patras 26500, Greece

[3] Aristotle Univ Thessaloniki, Dept Chem, Lab Appl Quantum Chem, GR-54006 Thessaloniki, Greece

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 20期

关键词：

D O I：

10.1021/ic991169k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

'Blends' of 2,2'-pyridil, (2-C5>H4>N)C(O)C(O)(2-C5>H4>N), and carboxylate ligands, R'CO2-, in alcohols (ROH) at room temperature are used to produce three clusters of the general formula [Cu5(OH)2{[(2-C5H4N)C(O)-(OR)C(O)(OR)(2-C5H4N)}2>(O2>CR')4>(ROH)2 >]. The five Cu(II) atoms are coplanar, exhibiting a rectangular arrangement of four metal ions with the fifth at the center of the rectangle. The representative complex with R = Et and R' = Me exhibits antiferromagnetic behavior.

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页码：4658 / 4662

页数：5

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