Asymmetric hydrogen transfer reduction of ketones using chiral perfluorinated ligands

被引：31

作者：

Maillard, D

Nguefack, C

Pozzi, G

Quici, S

Valadé, B

Sinou, D

机构：

[1] Univ Lyon 1, CNRS, CPE Lyon, Lab Synthese Asymetr, F-69622 Villeurbanne, France

[2] Ctr CNR Sintesi & Stereochim Speciali Sistemi Org, I-20133 Milan, Italy

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 14期

关键词：

D O I：

10.1016/S0957-4166(00)00249-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrogen transfer reduction of ketones occurs in a mixture of perfluoroalkane/isopropanol using iridium complexes in association with chiral perfluorosalen ligands. An enantioselectivity of up to 60% was obtained. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：2881 / 2884

页数：4

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