Fluoride-mediated phosphination of alkenes and alkynes by silylphosphines

被引：32

作者：

Hayashi, M ^{[1
]}

Matsuura, Y ^{[1
]}

Watanabe, Y ^{[1
]}

机构：

[1] Ehime Univ, Fac Engn, Dept Appl Chem, Matsuyama, Ehime 7908577, Japan

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 50期

关键词：

silylphosphine; phosphination; Michael addition; three-component coupling;

D O I：

10.1016/j.tetlet.2004.10.098

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Regioselective phosphination of carbon-carbon unsaturated bonds by a fluoride-mediated reaction of silylphosphines is described. Alkenes and alkynes having a directing group, such as an aromatic or a carbonyl group, reacted to form a carbon-phosphorus bond under mild conditions. When an anhydrous fluoride source was applied in the presence of an electrophile, the corresponding three-component coupling product was obtained. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：9167 / 9169

页数：3

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