Silane dendrimers containing titanium complexes on their periphery

被引：23

作者：

Arévalo, S ^{[1
]}

Benito, JM ^{[1
]}

de Jesús, E ^{[1
]}

de la Mata, FJ ^{[1
]}

Flores, JC ^{[1
]}

Gómez, R ^{[1
]}

机构：

[1] Univ Alcala de Henares, Dept Quim Inorgan, ES-28871 Madrid, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 602卷 / 1-2期

关键词：

silane dendrimers; titanium complexes; cyclopentadienyl complexes;

D O I：

10.1016/S0022-328X(00)00123-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrosilylation of 4-allyl-2-methoxyphenol (eugenol) with silane dendrimers of first or second generation and -SiMe2H ending groups affords new dendrimers with -SiMe2(CH2)(3)(C6H3(OMe)(OH)) terminating groups. The reaction of the hidroxy functionalities of these dendrimers with [CpTiCl3] (Cp = eta(5)-C5H5) provides an effective route for the attachment of cyclopentadienyl titanium complexes to the dendritic periphery. The yields of the prepared dendrimers with -SiMe2(CH2)(3)(C6H3(OMe)(OTiCl2Cp)) terminating groups are near quantitative. All the dendrimers are characterised by H-1-,C-13(H-1)-, and Si-29(H-1)-NMR spectroscopy, elemental analysis, and (except for Ti dendrimers) MALDI-TOF mass spectroscopy. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：208 / 210

页数：3

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