Structural variations of silver ethylene complexes supported by boron-protected fluorinated scorpionates and the isolation of a ligand-directed silver helix

被引：35

作者：

Dias, H. V. Rasika ^{[1
]}

Wu, Jiang ^{[1
]}

Wang, Xiaoyu ^{[1
]}

Rangan, Krishnan ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 06期

关键词：

D O I：

10.1021/ic062293o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silver(I) ethylene adducts [PhB(3-(CF3)Pz)(3)]Ag(C2H4) and [MeB(3-(CF3)Pz)(3)]Ag(C2H4) have been synthesized using the corresponding lithium salts, AgOTf, and ethylene. X-ray data show that [PhB(3-(CF3)Pz)(3)]Ag(C2H4) has a planar three-coordinate silver center whereas [MeB(3-(CF3)Pz)(3)]Ag(C2H4) features a tetrahedral silver site. The ethylene-free {[PhB(3-(CF3)Pz)(3)]Ag}(n) adopts a helical structure with a hexagonal pore.

引用

页码：1960 / 1962

页数：3

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