The hydrophobic effect as a driving force in the self-assembly of a [2x2] Copper(I) grid

被引：51

作者：

Nitschke, JR

Hutin, M

Bernardinelli, G

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland

[2] Univ Geneva, Lab X Ray Crystallog, CH-1211 Geneva 4, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 48期

关键词：

copper; dynamic combinatorial chemistry; Schiff bases; self-assembly; template synthesis;

D O I：

10.1002/anie.200461308

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spring-loaded supramolecular chemistry: Pyridine-2-carboxaldehyde reacts with the m-phenylenediamine shown in aqueous solution in the presence of Cu I ions to give a tetracopper(I) grid complex (see structure). ture). This structure is stable in water, but not in any of the organic solvents tried. The strain incorporated into the structure is compensated by a diffuse pressure applied by the hydrophobic effect. R = 2-hydroxyethylcarbamoyl.

引用

页码：6724 / 6727

页数：4

共 89 条

[1] From molecular diversity to template-directed self-assembly - New trends in metallo-supramolecular chemistry [J].