The hydrophobic effect as a driving force in the self-assembly of a [2x2] Copper(I) grid

被引：51

作者：

Nitschke, JR

Hutin, M

Bernardinelli, G

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland

[2] Univ Geneva, Lab X Ray Crystallog, CH-1211 Geneva 4, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 48期

关键词：

copper; dynamic combinatorial chemistry; Schiff bases; self-assembly; template synthesis;

D O I：

10.1002/anie.200461308

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spring-loaded supramolecular chemistry: Pyridine-2-carboxaldehyde reacts with the m-phenylenediamine shown in aqueous solution in the presence of Cu I ions to give a tetracopper(I) grid complex (see structure). ture). This structure is stable in water, but not in any of the organic solvents tried. The strain incorporated into the structure is compensated by a diffuse pressure applied by the hydrophobic effect. R = 2-hydroxyethylcarbamoyl.

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收藏

页码：6724 / 6727

页数：4

相关论文

共 89 条

[71] Adventures in molecular recognition. The ins and outs of templating [J].

Sanders, JKM .

PURE AND APPLIED CHEMISTRY, 2000, 72 (12) :2265-2274

[72] The advantage of being virtual-target-induced adaptation and selection in dynamic combinatorial libraries [J].

Severin, K .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (10) :2565-2580

[73] Selection and amplification of mixed-metal porphyrin cages from dynamic combinatorial libraries [J].

Stulz, E ;

Scott, SM ;

Bond, AD ;

Teat, SJ ;

Sanders, JKM .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (24) :6039-6048

[74] Complexes of 5,5′-aminoacido-substituted 2,2′-bipyridyl ligands:: control of diastereoselectivity with a pH switch and a chloride-responsive combinatorial library [J].

Telfer, SG ;

Yang, XJ ;

Williams, AF .

DALTON TRANSACTIONS, 2004, (05) :699-705

[75] Polynuclear coordination complexes - from dinuclear to nonanuclear and beyond [J].

Thompson, LK .

COORDINATION CHEMISTRY REVIEWS, 2002, 233 :193-206

[76]

Uppadine L.H, 2004, ANGEW CHEM, V116, P242, DOI [10.1002/ange.200352937, DOI 10.1002/ANGE.200352937]

[77] Protonic modulation of redox properties in ionisable [2x2] grid-like metalloarrays [J].

Uppadine, LH ;

Gisselbrecht, JP ;

Lehn, JM .

CHEMICAL COMMUNICATIONS, 2004, (06) :718-719

[78] Three-level synthetic strategy towards mixed-valence and heterometallic [2 x 2] gridlike arrays [J].

Uppadine, LH ;

Lehn, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (02) :240-243

[79] Magnetism of self-assembled mono- and tetranuclear supramolecular Ni2+ complexes [J].

Waldmann, O ;

Hassmann, J ;

Muller, P ;

Volkmer, D ;

Schubert, US ;

Lehn, JM .

PHYSICAL REVIEW B, 1998, 58 (06) :3277-3285

[80] Quantum magneto-oscillations in a supramolecular Mn(II)-[3 x 3] grid [J].

Waldmann, O ;

Carretta, S ;

Santini, P ;

Koch, R ;

Jansen, AGM ;

Amoretti, G ;

Caciuffo, R ;

Zhao, L ;

Thompson, LK .

PHYSICAL REVIEW LETTERS, 2004, 92 (09) :096403-1

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