The first example of Nazarov reactions of vinyl cumulenyl ketones

被引：42

作者：

Leclerc, L

Tius, MA

机构：

[1] Univ Hawaii, Dept Chem, Honolulu, HI 96822 USA

[2] Canc Res Ctr Hawaii, Honolulu, HI 96813 USA

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 08期

关键词：

D O I：

10.1021/ol034110x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

alpha-Lithio cumulenyl ethers can be prepared in situ and converted to alpha-allenyl cyclopentenones. Isomerization of the product of one such reaction has led to a furanyl cyclopentenone, the core structure of nakadomarin A.

引用

页码：1171 / 1174

页数：4

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