Electrochemical synthesis of nanosize polyaniline from aqueous surfactant solutions

被引：28

作者：

Raj, Jeyaraman Anandha ^{[1
]}

Mathiyarasu, Jayaraman ^{[2
]}

Vedhi, Chinnapiyan ^{[3
]}

Manisankar, Paramasivam ^{[1
]}

机构：

[1] Alagappa Univ, Sch Chem, Dept Ind Chem, Karaikkudi 630003, Tamil Nadu, India

[2] Cent Electrochem Res Inst, Electrod & Electrocatalysis Div, Karaikkudi 630006, Tamil Nadu, India

[3] VO Chidambaram Coll, Dept Chem, Tuticorin 628008, Tamil Nadu, India

来源：

MATERIALS LETTERS | 2010年 / 64卷 / 08期

关键词：

Polyaniline; Surfactant; Atomic force microscopy; Nanomaterials; BEHAVIOR; ROUTE;

D O I：

10.1016/j.matlet.2010.01.019

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electrochemical polymerization of aniline was carried out in micellar solutions of camphor sulphonic acid (CSA, anionic surfactant), cetyltrimethylammonium bromide (CTAB, cationic surfactant) and TritonX 100 (Tx100, nonionic surfactant), to reveal the morphology against the nature of the surfactant molecule. The resultant polyaniline film was characterized by Fourier transform infrared (FTIR) spectroscopic and cyclic voltammetric techniques. The surface morphology observed from different surfactant molecules was found to be distinctly different. Polyaniline synthesized from CSA and Tx100 solutions, showed uniform nanosized (100 nm) globular structures. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：895 / 897

页数：3

共 22 条

[1] Influence of the thickness of electrochemically deposited polyaniline used as hole transporting layer on the behaviour of polymer light-emitting diodes [J].

Alonso, J. L. ;

Ferrer, J. C. ;

Cotarelo, M. A. ;

Montilla, F. ;

de Avila, S. Fernandez .

THIN SOLID FILMS, 2009, 517 (08) :2729-2735

[2] Self-assembled polyaniline nanorods synthesized by facile route of dispersion polymerization [J].

Bhadra, J. ;

Sarkar, D. .

MATERIALS LETTERS, 2009, 63 (01) :69-71

[3] AFM morphological study of electropolymerised polyaniline films modified by surfactant and large anions [J].

Giz, MJ ;

Maranhao, SLD ;

Torresi, RM .

ELECTROCHEMISTRY COMMUNICATIONS, 2000, 2 (06) :377-381

[4] Preparation of polyaniline nanostructures using sodium dodecylsulphate [J].

Jeevananda, T. ;

Lee, Joong Hee ;

Siddaramaiah .

MATERIALS LETTERS, 2008, 62 (24) :3995-3998

[5] Synthesis of polyaniline/Ag composite nanospheres through UV rays irradiation method [J].

Li, Xia ;

Gao, Yu ;

Liu, Fuhong ;

Gong, Jian ;

Qu, Lunyu .

MATERIALS LETTERS, 2009, 63 (3-4) :467-469

[6]

MANIGANDANS S, 2008, MATER LETT, V6, P2535

[7] Copolymerization of aniline and 4,4′-diaminodiphenyl sulphone and characterization of formed nano size copolymer [J].

Manisankar, P. ;

Vedhi, C. ;

Selvanathan, G. ;

Prabu, H. Gurumallesh .

ELECTROCHIMICA ACTA, 2006, 52 (03) :831-838

[8] Electrochemical synthesis and characterization of novel electrochromic poly (3,4-ethylenedioxythiophene-co-Diclofenac) with surfactants [J].

Manisankar, P ;

Vedhi, C ;

Selvanathan, G ;

Prabu, HG .

ELECTROCHIMICA ACTA, 2006, 51 (14) :2964-2970

[9] Electrochemical and electrochromic behavior of novel poly(aniline-co-4,4′-diaminodiphenyl sulfone) [J].

Manisankar, P ;

Vedhi, C ;

Selvanathan, G ;

Somasundaram, RM .

CHEMISTRY OF MATERIALS, 2005, 17 (07) :1722-1727

[10] Inkjet printable polyaniline nanoformulations [J].

Ngamna, Orawan ;

Morrin, Aoife ;

Killard, Anthony J. ;

Moulton, Simon E. ;

Smyth, Malcolm R. ;

Wallace, Gordon G. .

LANGMUIR, 2007, 23 (16) :8569-8574

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