Tandem catalysis: a taxonomy and illustrative review

被引:861
作者
Fogg, DE
dos Santos, EN
机构
[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada
[2] Univ Ottawa, Ctr Catalysis Res & Innovat, Ottawa, ON K1N 6N5, Canada
基金
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词
catalysis; tandem catalysis; classification; cascade catalysis; domino catalysis; orthogonal catalysis; olefin metathesis; hydroformylation;
D O I
10.1016/j.ccr.2004.05.012
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A scheme is advanced for the classification of one-pot, coupled catalytic transformations, which distinguishes between one-pot, domino/ cascade, and tandem catalysis. The last of these is divided into three subclasses: orthogonal, auto-tandem, and assisted tandem catalysis. The proposed taxonomy, and the potential of tandem catalysis in organic synthesis, are illustrated with examples drawn from olefin metathesis and hydroformylation chemistry. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:2365 / 2379
页数:15
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