Amines made easily: A highly selective hydroaminomethylation of olefins

被引：204

作者：

Ahmed, M ^{[1
]}

Seayad, AM ^{[1
]}

Jackstell, R ^{[1
]}

Beller, M ^{[1
]}

机构：

[1] Univ Rostock EV, Leibniz Inst Organ Katalyse, IfOK, D-18055 Rostock, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 34期

关键词：

D O I：

10.1021/ja030143w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly chemo- and regioselective hydroaminomethylation of simple as well as functionalized alpha-olefins using a cationic rhodium precatalyst together with Xantphos as ligand is reported. Studies of the influence of ligands and reaction conditions led to an unprecedented selective hydroaminomethylation procedure. The novel procedure constitutes an economically attractive and environmentally favorable synthesis of secondary and tertiary aliphatic amines.

引用

页码：10311 / 10318

页数：8

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