Amines made easily: A highly selective hydroaminomethylation of olefins

被引:204
作者
Ahmed, M [1 ]
Seayad, AM [1 ]
Jackstell, R [1 ]
Beller, M [1 ]
机构
[1] Univ Rostock EV, Leibniz Inst Organ Katalyse, IfOK, D-18055 Rostock, Germany
关键词
D O I
10.1021/ja030143w
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly chemo- and regioselective hydroaminomethylation of simple as well as functionalized alpha-olefins using a cationic rhodium precatalyst together with Xantphos as ligand is reported. Studies of the influence of ligands and reaction conditions led to an unprecedented selective hydroaminomethylation procedure. The novel procedure constitutes an economically attractive and environmentally favorable synthesis of secondary and tertiary aliphatic amines.
引用
收藏
页码:10311 / 10318
页数:8
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