LiMnBO3/C: A Potential Cathode Material for Lithium Batteries

被引：31

作者：

Aravindan, V. ^{[2
]}

Karthikeyan, K. ^{[1
]}

Amaresh, S. ^{[1
]}

Lee, Y. S. ^{[1
]}

机构：

[1] Chonnam Natl Univ, Fac Appl Chem Engn, Kwangju 500757, South Korea

[2] Chonnam Natl Univ, Res Inst Catalysis, Kwangju 500757, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2010年 / 31卷 / 06期

关键词：

LiMnBO3; Carbon coating; Nano materials; Adipic acid; Impedance spectroscopy; ELECTROCHEMICAL PERFORMANCE; ELECTRODE MATERIALS; IRON PHOSPHATE; LIFEBO3;

D O I：

10.5012/bkcs.2010.31.6.1506

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

LiMnBO3 was successfully synthesized by a solid-state reaction method both with and without a carbon coating. Adipic acid was used as source material for the carbon coating. LiMnBO3 was composed of many small polycrystalline particles with a size of about 50-70 nm, which showed a very even particle morphology and highly ordered crystalline particulates. Whereas the carbon coated LiMnBO3 was well covered by mat-like, fine material consisting of amorphous carbon derived from the carbonization of adipic acid during the synthetic process. Carbon coated cell exhibited improved and stable discharge capacity profile over the untreated. Two cells delivered an initial discharge capacity of 111 and 58 mAh/g for LiMnBO3/C and LiMnBO3, respectively. Carbon coating on the surface of the LiMnBO3 drastically improved discharge capacity due to the improved electric conductivity in the LiMnBO3 material.

引用

页码：1506 / 1508

页数：3

共 13 条

[1] LiMBO3 (M=Fe, Mn):: Potential cathode for lithium ion batteries [J].