Corrosion study on different types of metallic bipolar plates for polymer electrolyte membrane fuel cells

被引:33
作者
Silva, R. F. [1 ]
Pozio, A. [1 ]
机构
[1] ENEA, CR Casaccia, I-00060 Rome, Italy
来源
JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY | 2007年 / 4卷 / 02期
关键词
stainless steel; Ni-based alloy; PVD coating; electrical resistance; PEMFC;
D O I
10.1115/1.2713768
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Three different types of metallic bipolar plates (commercial stainless steels, Ni-based alloys, and nitride-coated steels) were investigated in terms of their interface contact resistance (ICR) and corrosion resistance in conditions typical of a proton exchange membrane fuel cell environment. The results showed that stainless steels are unsuitable because of the formation of nonconductive oxide that leads to high ICR. Ni-based alloys showed to be prone to corrosion in acidic medium, although they have an ICR comparable to commercially available graphite. Endurance tests carried out on nitride-coated stainless-steel specimens showed a low ICR and very good corrosion resistance of this material.
引用
收藏
页码:116 / 122
页数:7
相关论文
共 25 条
[1]   Carbon/carbon composite bipolar plate for proton exchange membrane fuel cells [J].
Besmann, TM ;
Klett, JW ;
Henry, JJ ;
Lara-Curzio, E .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (11) :4083-4086
[2]   Preferential thermal nitridation to form pin-hole free Cr-nitrides to protect proton exchange membrane fuel cell metallic bipolar plates [J].
Brady, MP ;
Weisbrod, K ;
Paulauskas, I ;
Buchanan, RA ;
More, KL ;
Wang, H ;
Wilson, M ;
Garzon, F ;
Walker, LR .
SCRIPTA MATERIALIA, 2004, 50 (07) :1017-1022
[3]  
BUSICK DN, 1998, FUEL CELL SEM WASH D, P632
[4]   Stainless steel as a bipolar plate material for solid polymer fuel cells [J].
Davies, DP ;
Adcock, PL ;
Turpin, M ;
Rowen, SJ .
JOURNAL OF POWER SOURCES, 2000, 86 (1-2) :237-242
[5]  
Feng HP, 2003, MAT SCI ENG A-STRUCT, V347, P123, DOI 10.1016/S0921-5093(02)00578-6
[6]  
Gottesfeld S, 1997, ADV ELECTROCHEM SCI, V5, P195, DOI DOI 10.1002/9783527616794.CH4
[7]   Injection moulded low cost bipolar plates for PEM fuel cells [J].
Heinzel, A ;
Mahlendorf, F ;
Niemzig, O ;
Kreuz, C .
JOURNAL OF POWER SOURCES, 2004, 131 (1-2) :35-40
[8]   New materials for polymer electrolyte membrane fuel cell current collectors [J].
Hentall, PL ;
Lakeman, JB ;
Mepsted, GO ;
Adcock, PL ;
Moore, JM .
JOURNAL OF POWER SOURCES, 1999, 80 (1-2) :235-241
[9]   New lightweight bipolar plate system for polymer electrolyte membrane fuel cells [J].
Hodgson, DR ;
May, B ;
Adcock, PL ;
Davies, DP .
JOURNAL OF POWER SOURCES, 2001, 96 (01) :233-235
[10]   Bipolar plate materials development using Fe-based alloys for solid polymer fuel cells [J].
Hornung, R ;
Kappelt, G .
JOURNAL OF POWER SOURCES, 1998, 72 (01) :20-21