Isotope effects in C-H bond activation reactions by transition metals

被引：430

作者：

Jones, WD ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2003年 / 36卷 / 02期

关键词：

D O I：

10.1021/ar020148i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The activation of alkane C-H bonds by oxidative addition and its reverse reaction, reductive elimination, are believed to occur via transient a-alkane complexes. This Account summarizes how isotope effects can be used to probe the nature of these intermediates and points out some pitfalls in interpreting kinetic data. Comparisons are made with arene C-H activation and other activation systems.

引用

页码：140 / 146

页数：7

共 53 条

[11] New ansa-2,2-bis(eta-cyclopentadienyl)propane molybdenum and tungsten compounds and intramolecular hydrogen-deuterium exchange in methyl-hydride and ethyl-hydride derivatives
Chernega, A
Cook, J
Green, MLH
Labella, L
Simpson, SJ
Souter, J
Stephens, AHH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (18): : 3225 - 3243
[12] MULTIPLE ETA-2-ARENE COORDINATION - STRUCTURE AND ISOMERISM OF NAPHTHALENE COMPLEXES OF [(C5ME5)RH(PME3)]
CHIN, RM
DONG, LZ
DUCKETT, SB
JONES, WD
[J]. ORGANOMETALLICS, 1992, 11 (02) : 871 - 876
[13] PENTAAMMINEOSMIUM(II)-ETA-2-2,6-LUTIDINE - AN INTERMEDIATE FOR C-H ACTIVATION
CORDONE, R
TAUBE, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (26) : 8101 - 8102
[14] ASPECTS OF METHANE CHEMISTRY
CRABTREE, RH
[J]. CHEMICAL REVIEWS, 1995, 95 (04) : 987 - 1007
[15] REDUCTIVE ELIMINATION OF METHANE FROM A CATIONIC RHENIUM METHYL HYDRIDE - EVIDENCE FOR AN INTERMEDIATE METHANE COMPLEX
GOULD, GL
HEINEKEY, DM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (14) : 5502 - 5504
[16] Metal-alkane complexes.: Rapid exchange of hydrogen atoms between hydride and methyl ligands in [(C5Me5)Os(dmpm)(CH3)H+]
Gross, CL
Girolami, GS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (26) : 6605 - 6606
[17] ACTIVATION OF THE C-H BONDS OF BENZENE BY REACTION WITH [BIS(DICYCLOHEXYLPHOSPHINO)ETHANE]PLATINUM(0), GENERATED BY THE THERMOLYSIS OF CIS-[BIS(DICYCLOHEXYLPHOSPHINO)ETHANE]HYDRIDONEOPENTYL-PLATINUM(II)
HACKETT, M
IBERS, JA
WHITESIDES, GM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (05) : 1436 - 1448
[18] Transition metal alkane complexes
Hall, C
Perutz, RN
[J]. CHEMICAL REVIEWS, 1996, 96 (08) : 3125 - 3146
[19] REACTIVITY OF PENTAAMMINEOSMIUM(II) WITH BENZENE
HARMAN, WD
TAUBE, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (06) : 1883 - 1885
[20] SUBSTITUENT EFFECTS ON ETA-2-COORDINATED ARENE COMPLEXES OF PENTAAMMINEOSMIUM(II)
HARMAN, WD
SEKINE, M
TAUBE, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (17) : 5725 - 5731

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