Isotope effects in C-H bond activation reactions by transition metals

被引:430
作者
Jones, WD [1 ]
机构
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
关键词
D O I
10.1021/ar020148i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The activation of alkane C-H bonds by oxidative addition and its reverse reaction, reductive elimination, are believed to occur via transient a-alkane complexes. This Account summarizes how isotope effects can be used to probe the nature of these intermediates and points out some pitfalls in interpreting kinetic data. Comparisons are made with arene C-H activation and other activation systems.
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页码:140 / 146
页数:7
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