Photoemission study of energy-band alignment for RuOx/HfO2/Si system

被引:38
作者
Li, Q
Wang, SJ
Li, KB
Huan, ACH
Chai, JW
Pan, JS
Ong, CK
机构
[1] Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore
[2] Inst Mat Res & Engn, Singapore 117602, Singapore
[3] Data Storage Inst, Singapore 117608, Singapore
关键词
D O I
10.1063/1.1839287
中图分类号
O59 [应用物理学];
学科分类号
摘要
Conductive oxides RuOx as alternative electrode on high-kappa HfO2 gate dielectric have been fabricated by ultrahigh-vacuum sputtering and subsequently oxidized using oxygen plasma. The energy-band alignment for the RuOx/HfO2/Si system and the oxidation-state dependence of barrier height for RuOx contacting to HfO2 dielectrics has been analyzed by x-ray photoemission spectroscopy. The valence- and conduction-band offsets of HfO2/Si are determined to be 3.05+/-0.1 and 1.48+/-0.1 eV, respectively. The barrier heights for the RuOx contacting to HfO2 are oxidation-state dependent, in the range of 1.95-2.73 eV. (C) 2004 American Institute of Physics.
引用
收藏
页码:6155 / 6157
页数:3
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