Recent Advances in Ligand Design for the Intermolecular Asymmetric Mizoroki-Heck Reaction

被引：35

作者：

Coeffard, Vincent ^{[1
]}

Guiry, Patrick J. ^{[1
]}

机构：

[1] Univ Coll Dublin, Sch Chem & Chem Biol, Conway Inst Biomol Res, Ctr Synth & Chem Biol, Dublin 4, Ireland

来源：

CURRENT ORGANIC CHEMISTRY | 2010年 / 14卷 / 03期

基金：

爱尔兰科学基金会;

关键词：

PALLADIUM-CATALYZED ARYLATION; OXAZOLINE-CONTAINING LIGANDS; PLANAR CHIRAL DIPHOSPHINES; QUATERNARY CARBON CENTERS; MEO-BIPHEP; HETPHOX LIGANDS; ACYCLIC ALKENES; RESOLUTION; ARYL; 2,3-DIHYDROFURAN;

D O I：

10.2174/138527210790231928

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review deals with recent advances in ligand design for the intermolecular asymmetric Mizoroki-Heck reaction. Since the seminal report by Hayashi and co-workers in 1991 on the intermolecular asymmetric Mizoroki-Heck reaction, research on new and improved catalytic systems has become a field of growing interest. Over the last decade, efforts have been made to develop stable and easily synthesised ligands that induce high reactivity and selectivity (regio- and enantioselectivity) with a wide range of substrates. This review covers important developments in this field over the last decade by focusing on ligand design and applications. The article is organised according to the ligand class: [P,P], [P,N] and other ligand classes involved in the intermolecular asymmetric Mizoroki-Heck reaction.

引用

页码：212 / 229

页数：18

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