Bis(acetylide) complexes of ruthenium

被引：37

作者：

Field, LD ^{[1
]}

George, AV ^{[1
]}

Purches, GR ^{[1
]}

White, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6907,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 09期

关键词：

D O I：

10.1039/dt9960002011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of the form [Ru(C=CR')(2)(L-L)(2)] [L-L = R(2)PCH(2)CH(2)PR(2); R = Me (dmpe) or Et (depe); R' = Bu(t), Ph, 4-HC=CC6H4, 4-MeOC(6)H(4) or 3,5-(F3C)(2)C6H3] were prepared by reaction of [RuCl2(L-L)(2)] or [RuH2(L-L)(2)] with terminal acetylenes in methanol solution. The spectroscopic data indicate that the acetylide groups adopt a trans stereochemistry across the metal centre. The crystal structure of [Ru(C=CPh)(2)(dmpe)(2)] was determined.

引用

页码：2011 / 2016

页数：6

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