Microwave-assisted polymer synthesis: Recent developments in a rapidly expanding field of research

被引：333

作者：

Hoogenboom, Richard ^{[1
]}

Schubert, Ulrich S. ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2007年 / 28卷 / 04期

关键词：

microwave irradiation; polymer; radical polymerization; ring-opening polymerization; step-growth polymerization;

D O I：

10.1002/marc.200600749

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The use of microwave irradiation has become a common heat source in organic chemistry. Inspired by this enormous success, the use of microwave irradiation is also increasingly studied for polymerization reactions. The present review discusses developments in this rapidly growing field of research. The main areas in which the use of microwave irradiation has been explored in the recent years are step-growth polymerizations, ring-opening polymerizations as well as radical polymerizations. These different areas will be addressed in detail, whereby special attention will be given to observed improvements resulting from the use of microwave irradiation as well as the occurrence of non-thermal effects.

引用

页码：368 / 386

页数：19

共 118 条

[81]

OMEALEY J, 2006, J UNDERGRAD CHEM RES, V5, P89

[82] Scale-up of microwave-assisted polymerizations in continuous-flow mode: Cationic ring-opening polymerization of 2-ethyl-2-oxazoline [J].