Improvement of discharge capacity of LiCoO2 thin-film cathodes deposited in trench structure by liquid-delivery metalorganic chemical vapor deposition

被引:25
作者
Cho, SI [1 ]
Yoon, SG [1 ]
机构
[1] Chungnam Natl Univ, Dept Mat Engn, Taejon 305764, South Korea
关键词
D O I
10.1063/1.1571958
中图分类号
O59 [应用物理学];
学科分类号
摘要
Pt collector and LiCoO2 cathode films were deposited onto trench-SiO2/Si substrates by liquid-delivery metalorganic chemical vapor deposition (LDMOCVD). The 100-nm-thick Pt thin films deposited at 350 degreesC showed the lowest resistivity and roughness and step-coverage of 57% in trench structure (aspect ratio-1). The LiCoO2 cathode films (step-coverage=51%) deposited onto a Pt collector showed an increase of approximately two and half times the discharge capacity compared with those of planar-cathode films. The LDMOCVD process is suitable to improve the discharge capacity of LiCoO2 cathode films using a trench structure in lithium rechargeable batteries. (C) 2003 American Institute of Physics.
引用
收藏
页码:3345 / 3347
页数:3
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