Hydrated metal ions in the gas phase

被引:136
作者
Beyer, Martin K. [1 ]
机构
[1] Tech Univ Berlin, Inst Chem, Sekr C4, D-10623 Berlin, Germany
关键词
hydration; hydrogen formation; ion-molecule reaction; metal ion; solvation; water cluster;
D O I
10.1002/mas.20135
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Studying metal ion solvation, especially hydration, in the gas phase has developed into a field that is dominated by a tight interaction between experiment and theory. Since the studied species carry charge, mass spectrometry is an indispensable tool in all experiments. Whereas gas-phase coordination chemistry and reactions of bare metal ions are reasonably well understood, systems containing a larger number of solvent molecules are still difficult to understand. This review focuses on the rich chemistry of hydrated metal ions in the gas phase, covering coordination chemistry, charge separation in multiply charged systems, as well as intracluster and ion-molecule reactions. Key ideas of metal ion solvation in the gas phase are illustrated with rare-gas solvated metal ions. (c) 2007 Wiley Periodicals, Inc.
引用
收藏
页码:517 / 541
页数:25
相关论文
共 241 条
[91]   Structures, spectroscopies, and reactions of atomic ions with water clusters [J].
Fuke, K ;
Hashimoto, K ;
Iwata, S .
ADVANCES IN CHEMICAL PHYSICS, VOL 110, 1999, 110 :431-523
[92]  
Gilligan JJ, 2003, SP S CLUST PHYS, P101
[93]   Global minima and energetics of Li+(H2O), and Ca2+(H2O)n clusters for n≤20 [J].
González, BS ;
Hernández-Rojas, J ;
Wales, DJ .
CHEMICAL PHYSICS LETTERS, 2005, 412 (1-3) :23-28
[94]   CHEMISTRY AND KINETICS OF PRIMARY REACTIONS OF TI+ WITH H2O, NH3, CH3OH, C2H4, AND C3H6 AT THERMAL ENERGIES [J].
GUO, BC ;
KERNS, KP ;
CASTLEMAN, AW .
JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (12) :4879-4883
[95]   INTERACTION OF METHANOL WITH BRONSTED ACID SITES OF ZEOLITE CATALYSTS - AN AB-INITIO STUDY [J].
HAASE, F ;
SAUER, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (13) :3780-3789
[96]   Vibrational predissociation spectroscopy of the (H2O)-6-21clusters in the OH stretching region:: Evolution of the excess electron-binding signature into the intermediate cluster size regime -: art. no. 244311 [J].
Hammer, NI ;
Roscioli, JR ;
Bopp, JC ;
Headrick, JM ;
Johnson, MA .
JOURNAL OF CHEMICAL PHYSICS, 2005, 123 (24)
[97]   DEHYDROGENATION REACTIONS IN MG+(H2O)(N) CLUSTERS [J].
HARMS, AC ;
KHANNA, SN ;
CHEN, AB ;
CASTLEMAN, AW .
JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (05) :3540-3544
[98]   Experimental and theoretical investigation of microsolvation of Na+-ions in the gas phase by high resolution mass spectrometry and global cluster geometry optimization [J].
Hartke, B ;
Charvat, A ;
Reich, M ;
Abel, B .
JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (09) :3588-3600
[99]   SPECTROSCOPY OF ALAR AND ALKR FROM 31000 CM-1 TO THE IONIZATION LIMIT [J].
HEIDECKE, SA ;
FU, ZW ;
COLT, JR ;
MORSE, MD .
JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (03) :1692-1710
[100]  
Heinemann C, 1996, MOL PHYS, V89, P473, DOI 10.1080/00268979609482487