LOW PRESSURE OLIGOMERIZATION OF MONO-OLEFINS WITH SOLUBLE NICKEL-ALUMINUM BIMETAL CATALYSTS .2. REACTION KINETICS OF PROPENE DIMERIZATION

被引：28

作者：

ONSAGER, OT

WANG, H

BLINDHEI.U

机构：

[1] Zentralinstitut für Industrielle Forschung, Oslo, Blindern

来源：

HELVETICA CHIMICA ACTA | 1969年 / 52卷 / 01期

关键词：

D O I：

10.1002/hlca.19690520120

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of the dimerization of propene in organic solvents under the influence of a homogeneous catalyst containing π‐tetramethylcyclobutadiene‐nickel dichloride and a prereacted mixture of ethylaluminiumdichloride and tri‐n‐butylphosphin are reported. The primary reaction products are: 2‐methyl‐1‐pentene, 4‐methyl‐2‐pentene (cis/trans), 2,3‐dimethyl‐1‐butene and 2‐Hexene (cis/trans) The results are in accordance with a coordinative mechanism on nickel. New results on the reaction between ethylaluminiumdichloride and O, N and P containing electrondonors are also discussed. Copyright © 1969 Verlag GmbH & Co. KGaA, Weinheim

引用

收藏

页码：196 / &

相关论文

共 19 条

[1] KETONES FROM ACYL CHLORIDES AND ALKYL ALUMINUM CHLORIDES - A SELECTIVE KETO-ESTER SYNTHESIS [J].

ADKINS, H ;

SCANLEY, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (06) :2854-2856

[2] The molecular structures of the dimers of aluminum dimethyl chloride, aluminum dimethyl bromide, and aluminum trimethyl and of hexamethyldisilane [J].

Brockway, LO ;

Davidson, NR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1941, 63 :3287-3297

[3]

COATES GE, 1960, ORGANOMETALLIC COMPO, pCH3

[4]

CRIEGEE R, 1959, LIEBIGS ANN CHEM, V623, P1

[5] EIN NICKEL-KOMPLEX DES TETRAMETHYL-CYCLOBUTADIENS [J].

CRIEGEE, R ;

SCHRODER, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1959, 71 (02) :70-71

[6] PROPERTIES OF ELECTROLYTIC SOLUTIONS .41. CONDUCTANCE OF ALUMINUM BROMIDES IN METHYL BROMIDE ON ADDITION OF DIMETHYL ETHER [J].

JACOBER, WJ ;

KRAUS, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (07) :2409-2412

[7] VALENCE IN THE BORON HYDRIDES [J].

LIPSCOMB, WN .

JOURNAL OF PHYSICAL CHEMISTRY, 1957, 61 (01) :23-27

[8] THE STRUCTURES OF ELECTRON-DEFICIENT MOLECULES [J].

LONGUETHIGGINS, HC .

QUARTERLY REVIEWS, 1957, 11 (02) :121-133

[9] INTERACTION OF ETHYLALUMINUM DICHLORIDE WITH ORGANIC NITROGEN AND PHOSPHORUS COMPOUNDS IN 3-COMPONENT POLYOLEFIN CATALYSTS [J].

MCCONNELL, RL ;

MCCALL, MA ;

CASH, GO ;

JOYNER, FB ;

COOVER, HW .

JOURNAL OF POLYMER SCIENCE PART A-GENERAL PAPERS, 1965, 3 (6PA) :2135-+

[10] LOW PRESSURE OLIGOMERIZATION OF MONO-OLEFINS WITH SOLUBLE NICKEL/ALUMINUM BIMETAL CATALYSTS .1. DEVELOPMENT OF NEW CATALYST SYSTEMS BASED ON PI-CYCLOBUTADIENE-NICKEL(2) COMPOUNDS [J].

ONSAGER, OT ;

WANG, H ;

BLINDHEI.U .

HELVETICA CHIMICA ACTA, 1969, 52 (01) :187-&