TRANSITION-METAL RIMMED CALIXRESORCINARENE COMPLEXES

被引：83

作者：

XU, W ^{[1
]}

ROURKE, JP ^{[1
]}

VITTAL, JJ ^{[1
]}

PUDDEPHATT, RJ ^{[1
]}

机构：

[1] UNIV WESTERN ONTARIO,DEPT CHEM,LONDON,ON N6A 5B7,CANADA

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 01期

关键词：

D O I：

10.1021/ic00105a050

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A bowl-shaped calixresorcinarene 1 has been derivatized to incorporate four phosphonite units to give a phosphonitocavitand 2 and eight phosphinite units to give phosphinito-calixresorcinarene 3. These derivatives have been used as multidentate ligands to incorporate transition metals on the upper rim of the calixresorcinarene bowl. Several gold(I) complexes and platinum(II) complexes have been synthesized. The chlorogold(I) complex of 2, 2(AuCl)4, was characterized by an X-ray structure determination [crystal data: C84H68Au4Cl4P4O8.0.5CH(2)Cl(2).2.5CH(3)CN.H2O, fw = 2422.16, triclinic, P $($) over bar$$ 1, a = 15.271(5) Angstrom, b = 28.399(8) Angstrom, c = 11.060(5) Angstrom, alpha = 93.40(3)degrees, beta = 111.21(3)degrees, gamma = 98.41(2)degrees, V = 4390.8 Angstrom(3), Z = 2, R = 0.0534, R(w) = 0.0504]. This complex is shown to contain three AuCl units around the upper rim of the bowl with the fourth AuCl unit-folded inside the cavity. The gold(I)-rimmed bowl forms inclusion complexes with amines and alkali metal cations but not with other potential substrates.

引用

页码：323 / 329

页数：7

共 39 条

[31]

SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

[32] OXIDATIVE ADDITION IN COUPLING OF ALKYLGOLD(I) WITH ALKYL-HALIDES [J].