NONLINEAR EFFECTS INVOLVING 2 COMPETING PSEUDO-ENANTIOMERIC CATALYSTS - EXAMPLE IN ASYMMETRIC DIHYDROXYLATION OF OLEFINS

被引：40

作者：

ZHANG, SY ^{[1
]}

GIRARD, C ^{[1
]}

KAGAN, HB ^{[1
]}

机构：

[1] UNIV PARIS 11,INST CHIM MOLEC ORSAY,CNRS,SYNTHESE ASYMETR LAB,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 11期

关键词：

D O I：

10.1016/0957-4166(95)00344-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric catalysis in the case of a mixture of pseudo-enantiomeric ligands has been studied in the Sharpless asymmetric dihydroxylation of bis-(ortho-bromo)stiIbene. Nonlinear behaviours were observed in this situation, one spectacular case being evidenced ((DHQD)(2)-PHAL/PCB-DHQ mixtures).

引用

页码：2637 / 2640

页数：4

共 17 条

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