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DIFFUSIONAL DESATURATION OF ELECTRON-TRANSFER

被引：5
作者：
BURSHTEIN, AI
机构：
[1] Weizmann Institute of Science, 76100, Rehovot
[2] Institute of Chemical Kinetics and Combustion, Novosibirsk
来源：
JOURNAL OF CHEMICAL PHYSICS | 1993年 / 98卷 / 06期
关键词：
D O I：
10.1063/1.464975
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Noncontact electron transfer (in the Marcus inverted zone) during encounters of neutral reagents in solution is considered. It is shown by means of generalized encounter theory that the saturation of the transfer rate at short distances due to vibrational friction or the dynamical solvent effect is removed when diffusion is sped up and never appears in the kinetic limit.
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页码：4711 / 4717
页数：7
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