STEREOSELECTIVE REDUCTION OF ALPHA,BETA-EPOXY KETONES WITH SODIUM-BOROHYDRIDE IN THE PRESENCE OF CALCIUM-CHLORIDE OR LANTHANUM CHLORIDE - A PRACTICAL PREPARATION OF ERYTHRO-ALPHA,BETA-EPOXY ALCOHOLS

被引：34

作者：

TANIGUCHI, M ^{[1
]}

FUJII, H ^{[1
]}

OSHIMA, K ^{[1
]}

UTIMOTO, K ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DIV MED CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

TETRAHEDRON | 1995年 / 51卷 / 03期

关键词：

D O I：

10.1016/0040-4020(94)00967-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

erythro-Epoxy alcohols were prepared with high stereoselectivity by NaBH4 reduction of the corresponding alpha,beta-epoxy ketones in the presence of calcium chloride or lanthanum chloride regardless of the substituents on the epoxide ring.

引用

页码：679 / 686

页数：8

共 16 条

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