SYNTHESIS AND SURFACTANT PROPERTIES OF FLUOROALKYLATED OLIGOMERS CONTAINING CARBOXY GROUPS

被引：72

作者：

SAWADA, H ^{[1
]}

GONG, YF ^{[1
]}

MINOSHIMA, Y ^{[1
]}

MATSUMOTO, T ^{[1
]}

NAKAYAMA, M ^{[1
]}

KOSUGI, M ^{[1
]}

MIGITA, T ^{[1
]}

机构：

[1] GUNMA UNIV,FAC ENGN,DEPT APPL CHEM,KIRYU,GUNMA 376,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 07期

关键词：

D O I：

10.1039/c39920000537

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of acrylic acid with various of difluoroalkanoyl peroxides {(R(f)CO2)2, R(f) = C3F7, C6F13, CF(CF3)[OCF2CF(CF3)]mOC3F7, m = 0, 1, 2} have been found to give new fluoroalkylated oligomers containing carboxy groups {R(f)[CH2CH(CO2H](n)R(f)} under mild conditions, and these compounds are able to reduce the surface tension of water to 10 mN m-1 levels.

引用

页码：537 / 538

页数：2

共 9 条

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