5-COORDINATE HYDRIDO-COMPLEXES [PTX(H)(N,N-CHELATE)(OLEFIN)] (X=CL, BR OR I) - CRYSTAL-STRUCTURE OF [PTCL(H)(2,9-ME2-1,10-PHENANTHROLINE)(DIMETHYL-MALEATE)]

被引：16

作者：

ALBANO, VG

CASTELLARI, C

FERRARA, ML

PANUNZI, A

RUFFO, F

机构：

[1] UNIV NAPOLI FEDERICO 2,DIPARTIMENTO CHIM,VIA MEZZOCANNONE 4,I-80134 NAPLES,ITALY

[2] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 469卷 / 02期

关键词：

PLATINUM; HYDRIDE; ALKENE; OXIDATIVE ADDITION;

D O I：

10.1016/0022-328X(94)88078-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compounds were obtained by oxidative addition of hydrogen halides to suitable [Pt(N,N-chelate)(olefin)] species. The properties of the ligands and of the electrophile which allow the isolation of stable products must meet very strict requirements. The crystal structure of [PtCl(H)(2,9-Me2-1,10-phenanthroline)(dimethyl maleate)] was determined by single-crystal X-ray diffraction. Substitution, insertion, and elimination reactions were performed on one hydride complex.

引用

页码：237 / 244

页数：8

共 25 条

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