ADSORBATE-INDUCED RELAXATIONS OF CLOSE-PACKED FCC AND HCP METAL-SURFACES

被引：46

作者：

STARKE, U

VANHOVE, MA

SOMORJAI, GA

机构：

[1] LAWRENCE BERKELEY LAB,DIV MAT SCI,BERKELEY,CA 94720

[2] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

来源：

PROGRESS IN SURFACE SCIENCE | 1994年 / 46卷 / 2-3期

关键词：

D O I：

10.1016/0079-6816(94)90088-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We review results and trends regarding the structural relaxations due to atoms and molecules adsorbed on close-packed surfaces of fcc and hcp metals. One observes primarily a buckling of the two topmost metal layers. Sometimes lateral relaxations are seen in the top layers, mostly radially away from or towards the adsorption site, and occasionally rotationally around the adsorption site. Such relaxations exhibit the local nature of the adsorbate-substrate bond and thus support a cluster-like view of surface bonding. These relaxations may play an important role in catalysis and other surface processes.

引用

页码：305 / 319

页数：15

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