AN INTRAMOLECULAR DIELS-ALDER APPROACH TO ANGULARLY TRIFLUOROMETHYLATED C/D CIS ESTRANES

被引：14

作者：

BLAZEJEWSKI, JC

HADDAD, M

WAKSELMAN, C

机构：

[1] CNRS-CERCOA, 94320 Thiasis

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 10期

关键词：

ANGULAR TRIFLUOROMETHYL GROUP; 18; 18-TRIFLUOROSTEROID; INTRAMOLECULAR DIELS-ALDER REACTION; O-QUINODIMETHANE;

D O I：

10.1016/S0040-4039(00)91598-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of 3-O-Methyl-14-beta-hydroxy-18,18,18-trifluoroestrone via the thermally induced intramolecular cyclisation of an orthoquinodimethane is described.

引用

页码：1269 / 1272

页数：4

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