AN EASY ACCESS TO STEREODEFINED 2-PENTENYLTINS BY PARTIAL HYDROGENATION OF 2,4-PENTADIENYLTINS WITH DIAZENE

被引：5

作者：

NISHIGAICHI, Y

ISHIDA, N

TAKUWA, A

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 01期

关键词：

D O I：

10.1246/bcsj.67.274

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tributyl- (2-pentenyl)tins were readily prepared in high yield by hydrogenation of tributyl-(2,4-pentadienyl)tins with diazene generated from 2,4,6-triisopropylbenaenesulfonohydrazide. The terminal double bond was selectively hydrogenated in the conjugated diene system. The stereochemistry of the internal double bond was completely retained.

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页码：274 / 276

页数：3

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