NOVEL ALLENYLIDENE ALKYNYL AND AMMONIA ALKYNYL METAL-COMPLEXES VIA SELECTIVE SYNTHESIS OF MONO AND BIS ALKYNYL RUTHENIUM(II) COMPLEXES - CRYSTAL-STRUCTURE OF TRANS-[RU(NH3)(C-EQUIVALENT-TO-CPH)(PH2PCH2CH2PPH2)2]PF6

被引：69

作者：

TOUCHARD, D ^{[1
]}

MORICE, C ^{[1
]}

CADIERNO, V ^{[1
]}

HAQUETTE, P ^{[1
]}

TOUPET, L ^{[1
]}

DIXNEUF, PH ^{[1
]}

机构：

[1] UNIV RENNES 1,PHYS CRISTALLINE LAB,CNRS,URA 804,F-35042 RENNES,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 07期

关键词：

D O I：

10.1039/c39940000859

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The activation of terminal alkynes with cis-[RuCl2(Ph2PCH2CH2PPh2)2] leads either to mono alkynyl, via vinylidene complex, or to bis alkynyl ruthenium complexes that are the key precursors of trans-[Ru(NH3)(C=CR)-(Ph2PCH2CH2PPh2)2]PF6 and [(Ph2C=C=C=RuC=CPh)(Ph2PCH2CH2PPh2)2]PF6 derivatives.

引用

页码：859 / 860

页数：2

共 12 条

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