4-METHYL-1,4-THIABORIN, AN AROMATIC BORON-SULFUR HETEROCYCLE

被引：13

作者：

ASHE, AJ

KAMPF, JW

WAAS, JR

机构：

[1] Department of Chemistry, University of Michigan, Ann Arbor

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 07期

关键词：

D O I：

10.1021/om00007a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The base-catalyzed hydrostannation of di-ethynyl sulfide with dibutylstannane affords 4,4-dibutyl-1,4-thiastannin, which reacts with methylboron dibromide to give 4-methyl-1,4-thiaborin. The thiaborin has been converted to tricarbonyl(eta(6)-4-methyl-1,4-thiaborin)-molybdenum, which has been characterized by single-crystal X-ray diffraction.

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页码：3141 / 3142

页数：2

相关论文

共 29 条

[1] CONFORMATIONAL PREFERENCES OF SUBSTITUTED CYCLOPENTADIENYL AND HETEROCYCLOPENTADIENYL COMPLEXES [J].

ALBRIGHT, TA ;

HOFFMANN, R .

CHEMISCHE BERICHTE-RECUEIL, 1978, 111 (04) :1578-1590

[2] STRUCTURAL ASPECTS OF THIOPHENE COORDINATION IN TRANSITION-METAL COMPLEXES [J].

ANGELICI, RJ .

COORDINATION CHEMISTRY REVIEWS, 1990, 105 :61-76

[3] HETEROGENEOUS CATALYSIS OF THE HYDRODESULFURIZATION OF THIOPHENES IN PETROLEUM - AN ORGANOMETALLIC PERSPECTIVE OF THE MECHANISM [J].

ANGELICI, RJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (11) :387-394

[4] EVALUATION OF THE AROMATICITY OF BOREPIN - SYNTHESIS AND PROPERTIES OF 1-SUBSTITUTED BOREPINS [J].

ASHE, AJ ;

KLEIN, W ;

ROUSSEAU, R .

ORGANOMETALLICS, 1993, 12 (08) :3225-3231

[5] 1-PHENYLBORABENZENE ANION [J].

ASHE, AJ ;

SHU, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (07) :1804-&

[6]

ASHE AJ, 1992, ANGEW CHEM INT EDIT, V31, P1255, DOI 10.1002/anie.199212551

[7] STRUCTURAL EVIDENCE OF THE AROMATICITY OF BOREPINS - A COMPARISON OF 1-CHLOROBOREPIN AND TRICARBONYL(1-CHLOROBOREPIN)MOLYBDENUM [J].

ASHE, AJ ;

KAMPF, JW ;

KLEIN, W ;

ROUSSEAU, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (07) :1065-1066

[8] 1-METHYL-4,5-CYCLOPENTENOBOREPIN - A NEUTRAL BORON ANALOG OF TROPYLIUM [J].

ASHE, AJ ;

DRONE, FJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (06) :1879-1880

[9] SYNTHESIS AND MOLECULAR AND CRYSTAL-STRUCTURES OF (3-METHYL-3-BENZOBOREPIN)CHROMIUM TRICARBONYL [J].

ASHE, AJ ;

KAMPF, JW ;

KAUSCH, CM ;

KONISHI, H ;

KRISTEN, MO ;

KROKER, J .

ORGANOMETALLICS, 1990, 9 (11) :2944-2948

[10]

ASHE AJ, 1988, J AM CHEM SOC, V110, P6599, DOI 10.1021/ja00227a070