CATALYTIC ASYMMETRIC HYDROSILYLATION OF 1,3-DIENES WITH DIFLUORO(PHENYL)SILANE

被引：30

作者：

OHMURA, H

MATSUHASHI, H

TANAKA, M

KUROBOSHI, M

HIYAMA, T

HATANAKA, Y

GODA, K

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 226,JAPAN

[2] SAGAMI CHEM RES CTR,SAGAMIHARA,KANAGAWA 229,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 499卷 / 1-2期

关键词：

CHIRALITY; FLUORINE; SILANE; FERROCENE; SILICON; PALLADIUM;

D O I：

10.1016/0022-328X(95)00311-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A palladium complex with an optically active ligand catalyzes asymmetric hydrosilylation of 1,3-dienes using difluoro(phenyl)silane to give optically active allyl difluoro(phenyl)silanes in good enantiomeric excess.

引用

页码：167 / 171

页数：5

共 11 条

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