FUNCTIONALIZATION OF SILICA .2. OXIDATION OF CYCLOHEXANES IN THE PRESENCE OF FUNCTIONALIZED SILICA COMPLEXED BY IRON AND COPPER

被引：3

作者：

KURUSU, Y

机构：

[1] Department of Chemistry, Sophia University, Tokyo, 102, 7-1, Chiyoda-ku

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1992年 / 59卷

关键词：

D O I：

10.1002/masy.19920590125

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Silica gel was modified with (N,N-dimethyl-3-aminopropyl)trimethoxysilane and the functionalized silica catalysts thus prepared complexed with iron and copper to produce FS-1{Fe},FS-1{Cu}. 11.2% of methylcyclohexane was oxidized in the presence of oxygen with FS-1(Fe) at 60-degrees-C. 2-Hydroxymethylcyclohexane was obtained in 59% yield. The structural differences between FS-1{Fe}and FS-1{Cu} are discussed.

引用

页码：313 / 318

页数：6

共 5 条

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[2]

JIN RH, IN PRESS J MOL CATAL

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