BIOCATALYTIC SYNTHESIS OF (S)-2-TRIDECANYL ACETATE AND (S)-2-PENTADECANYL ACETATE, AGGREGATION PHEROMONE COMPONENTS OF DROSOPHILA-MULLERI AND D-BUSCKII, BY ENANTIOSELECTIVE HYDROLYSIS WITH LIPASE

被引：8

作者：

KAMEZAWA, M

TACHIBANA, H

OHTANI, T

NAOSHIMA, Y

机构：

[1] KONAN CHEM IND CO LTD,5-21 NAKAGAWA CHO,TAKATSUKI,OSAKA 569,JAPAN

[2] OKAYAMA UNIV SCI,FAC SCI,DEPT BIOCHEM,OKAYAMA 700,JAPAN

来源：

JOURNAL OF CHEMICAL ECOLOGY | 1994年 / 20卷 / 05期

关键词：

DROSOPHILA-MULLERI; D-BUSCKII; DIPTERA; DROSOPHILIDAE; AGGREGATION PHEROMONE; (S)-2-TRIDECANYL ACETATE; (S)-2-PENTADECANYL ACETATE; LIPASE; HYDROLYSIS; ENANTIOSELECTIVITY; CHIRALITY;

D O I：

10.1007/BF02059742

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The two chiral pheromone acetates, (S)-2-tridecanyl acetate and (S)-2-pentadecanyl acetate, were synthesized with an enantiomeric excess (e.e.) of almost 100% by Pseudomonas cepacia lipase-catalyzed hydrolysis of their corresponding racemic acetates in an acetone-water solvent system.

引用

收藏

页码：1057 / 1061

页数：5

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