MULTISTEP REVERSIBLE REDOX SYSTEMS .58. 2,5-BIS(CYANOIMINO)-2,5-DIHYDROTHIENO[3,2-B]THIOPHENES - A NEW ACCEPTOR TYPE - SYNTHESIS AND COMMON PROPERTIES

被引:5
作者
GUNTHER, E [1 ]
HUNIG, S [1 ]
机构
[1] UNIV WURZBURG,INST ORGAN CHEM,HUBLAND,W-8700 WURZBURG,GERMANY
来源
CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 05期
关键词
REDOX SYSTEMS; ELECTRON TRANSFER; HETEROQUINONES; ELECTRON ACCEPTORS; THIENO[3,2-B]THIOPHENE DERIVATIVES;
D O I
10.1002/cber.19921250533
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of a variety of substituted 2,5-bis(cyanoimino)-2,5-dihydrothieno[3,2-b]thiophenes (4) and the corresponding diones (5) is described. Different substituents on the acceptors 4 and 5 allow the redox potentials of these reversible two-step redox systems to be varied over a wide range.
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页码:1235 / 1241
页数:7
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