OXIDATION OF FLAVANONES USING THALLIUM(III) SALTS - A NEW ROUTE FOR THE SYNTHESIS OF FLAVONES AND ISOFLAVONES

被引：37

作者：

KHANNA, MS ^{[1
]}

SINGH, OV ^{[1
]}

GARG, CP ^{[1
]}

KAPOOR, RP ^{[1
]}

机构：

[1] KURUKSHETRA UNIV,DEPT CHEM,KURUKSHETRA 132119,HARYANA,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 19期

关键词：

D O I：

10.1039/p19920002565

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

When treated with thallium(III) acetate in acetic acid or acetonitrile, flavanones undergo facile dehydrogenation to afford flavones whereas, upon treatment with thallium(III) toluene-p-sulfonate or thallium(III) nitrate in propionitrile or acetonitrile, respectively, they undergo oxidative 2,3-aryl migration to give isoflavones in high yield.

引用

页码：2565 / 2568

页数：4

共 36 条

[31] OXIDATIVE 1,2-ARYL REARRANGEMENT IN FLAVANONES USING THALLIUM(III) PARA-TOLYL SULFONATE (TTS) - A NEW USEFUL ROUTE TO ISOFLAVONES
SINGH, OV
GARG, CP
KAPOOR, RP
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[32] DEHYDROGENATION OF FLAVANONES TO FLAVONES USING THALLIUM(III) ACETATE (TTA)
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KAPOOR, RP
[J]. TETRAHEDRON LETTERS, 1990, 31 (10) : 1459 - 1462
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[36] OXIDATION OF FLAVANONES WITH THALLIUM(III) NITRATE(TTN) - A CONVENIENT ROUTE TO FLAVONES
VARMA, RS
VARMA, M
[J]. SYNTHETIC COMMUNICATIONS, 1982, 12 (12) : 927 - 930

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