ASYMMETRIC HECK REACTION - A CATALYTIC ASYMMETRIC-SYNTHESIS OF THE KEY INTERMEDIATE FOR VERNOLEPIN

被引：63

作者：

KONDO, K

SODEOKA, M

MORI, M

SHIBASAKI, M

机构：

[1] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

[2] HOKKAIDO UNIV,FAC PHARMACEUT SCI,KITA KU,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 26期

关键词：

D O I：

10.1016/S0040-4039(00)60532-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enone 5a, a functionalized decalin derivative, has been synthesized in pu to 86% ee by an asymmetric Heck reaction starting with the allylic alcohol 3. Enone 5a was converted to a key intermediate for vernolepin.

引用

页码：4219 / 4222

页数：4

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