TRANSITION-STATES FOR THE HYDROGEN-ATOM ABSTRACTION REACTION BY ALPHA-OXYGEN SUBSTITUTED RADICALS - FELKIN-ANH RULE IN RADICAL CHEMISTRY

被引：28

作者：

DAMM, W ^{[1
]}

DICKHAUT, J ^{[1
]}

WETTERICH, F ^{[1
]}

GIESE, B ^{[1
]}

机构：

[1] UNIV BASEL,INST ORGAN CHEM,ST JOHANNS RING 19,CH-4056 BASEL,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 03期

关键词：

STEREOCHEMISTRY; RADICALS; ABINITIO CALCULATIONS; TRANSITION STATES; CONFORMATIONAL ANALYSIS; ESR-SPECTROSCOPY;

D O I：

10.1016/0040-4039(93)85094-D

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ab initio calculations on transition states of the hydrogen atom abstration by alpha-oxygen substituted radicals show that the Felkin-Anh rule can be applied to radical chemistry.

引用

页码：431 / 434

页数：4

共 11 条

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[J]. TETRAHEDRON LETTERS, 1993, 34 (03) : 427 - 430
[8] Frisch M. J, 1992, GAUSSIAN 92
[9] CRAM'S RULE FOR RADICAL REACTIONS
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[J]. TETRAHEDRON LETTERS, 1991, 32 (43) : 6097 - 6100
[10] THEORY AND MODELING OF STEREOSELECTIVE ORGANIC-REACTIONS
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